HPLC-MS/MS法测定烟用接装纸中的六价铬含量

doi:10.14088/j.cnki.issn0439-8114.2022.11.026

湖北农业科学 ›› 2022, Vol. 61 ›› Issue (11): 128-132.doi: 10.14088/j.cnki.issn0439-8114.2022.11.026

HPLC-MS/MS法测定烟用接装纸中的六价铬含量

韩维岐, 王洋, 谷超林, 朱良华, 金哲

吉林烟草工业有限责任公司技术研发中心,长春 130031

收稿日期:2021-07-23 出版日期:2022-06-10 发布日期:2022-07-06
作者简介:韩维岐（1985-）,男,山东聊城人,工程师,硕士,主要从事卷烟及烟用材料研究,（电话）13756518132（电子信箱）hanweiqichina@163.com。
基金资助:
吉林烟草工业有限责任公司科技项目

Determination of hexavalent chromium in cigarette tipping paper by HPLC-MS/MS

HAN Wei-qi, WANG Yang, GU Chao-lin, ZHU Liang-hua, JIN Zhe

Technology R & D Center, Jilin Tobacco Industry Co., Ltd., Changchun 130031,China

Received:2021-07-23 Online:2022-06-10 Published:2022-07-06

摘要/Abstract

摘要： 建立了烟用接装纸中六价铬的HPLC-MS/MS测定方法。采用pH 8.0的氨水溶液超声萃取样品,过滤后直接检测。结果表明,六价铬线性相关系数在0.999以上,检出限为3 μg/kg,加标回收率为90.1%~106.9%,RSD为4.1%~7.8%。该方法与现行行业标准方法相比,前处理更加简单、快速,检测灵敏度更高,检出限更低,稳定性更好,适用于烟用接装纸中六价铬含量的测定。

关键词: 烟用接装纸, 六价铬, HPLC-MS/MS

Abstract: A HPLC-MS/MS method for the determination of hexavalent chromium in cigarette tipping paper was established. The samples were ultrasonically extracted with ammonia solution at pH 8.0 and directly detected after filtration. The results showed that the linear correlation coefficient of hexavalent chromium was above 0.999, the detection limit was 3 μg/kg, the recovery rate was 90.1%~106.9%, and RSD was 4.1%~7.8%. Compared with the current industrial standard method, this method is more simple and rapid, with higher detection sensitivity, lower detection limit and better stability, which is suitable for the determination of hexavalent chromium content in cigarette tipping paper.

Key words: cigarette tipping paper, hexavalent chromium, HPLC-MS/MS

中图分类号:

韩维岐, 王洋, 谷超林, 朱良华, 金哲. HPLC-MS/MS法测定烟用接装纸中的六价铬含量[J]. 湖北农业科学, 2022, 61(11): 128-132.

HAN Wei-qi, WANG Yang, GU Chao-lin, ZHU Liang-hua, JIN Zhe. Determination of hexavalent chromium in cigarette tipping paper by HPLC-MS/MS[J]. HUBEI AGRICULTURAL SCIENCES, 2022, 61(11): 128-132.

参考文献

[1] 侯宏卫,朱风鹏,唐纲岭,等.电感耦合等离子体质谱法快速测定烟用接装纸中砷、铅、镉、铬、镍、汞的研究[J].中国烟草学报,2009,15(4):8-12.
[2] YQT 60—2015,烟用接装纸六价铬测定连续流动法[S].
[3] 周峰,汤晓东,葛萍花,等.高效液相色谱法测定烟用接装纸中的六价铬[J].分析测试技术与仪器,2018,24(3):183-187.
[4] ALKAN U,ANDERSON G K,INCE O.Toxicity of trivalent chromium in the anaerobic digestion process[J]. Water research,1996, 30(3):731-741.
[5] STACEY N H,WONG K L,KLAASSEN C D.Protective effects of chromium on the toxicity of cadmium in vivo[J]. Toxicology,1983,28(1-2):147-153.
[6] VIGNATI D A L,DOMINIK J,BEYE M L,et al. Chromium(VI) is more toxic than chromium(III) to freshwater algae: A paradigm to revise?[J]. Ecotoxicology and environmental safety,2010,73(5):743-749.
[7] ROSSI E,ERREA M I,CORTALEZZI M M F D,et al. Selective determination of Cr (VI) by on-line solid phase extraction FI-SPE-FAAS using an ion exchanger resin as sorbent: An improvement treatment of the analytical signal[J]. Microchemical journal,2017,130:88-92.
[8] PETTINE M,CAPRI S.Digestion treatments and risks of Cr(III)-Cr(VI) interconversions during Cr(VI) determination in soils and sediments—a review[J]. Analytica Chimica Acta,2005,540(2):231-238.
[9] HASSAN S S M,ABDEL-SHAFI A A,MOHAMMED A H K. Flow injection fluorimetric determination of chromium(VI) in electroplating baths by luminescence quenching of tris(2,2′-bipyridyl) ruthenium(II)[J]. Talanta,2005,67(4):696-702.
[10] KRISHNA M V B,CHANDRASEKARAN K,RAO S V,et al. Speciation of Cr(III) and Cr(VI) in waters using immobilized moss and determination by ICP-MS and FAAS[J]. Talanta,2004, 65(1):135-143.
[11] GANESHJEEVAN R,CHANDRASEKAR R,YUVARAJ S,et al.Determination of hexavalent chromium by on-line dialysis ion chromatography in a matrix of strong colourants and trivalent chromium[J]. Journal of chromatography A,2003,988(1):151-159.
[12] 罗东辉,罗海英,吴文海,等.高效液相色谱法测定明胶中的六价铬[J].现代食品科技,2012,28(8):1091-1093.
[13] 许永,杨光宇,刘欣,等.快速测定彩色卷烟纸与接装纸中六价铬的连续流动分析方法[J].分析测试学报,2018,37(12):1480-1484.

HPLC-MS/MS法测定烟用接装纸中的六价铬含量

Determination of hexavalent chromium in cigarette tipping paper by HPLC-MS/MS

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 0

编辑推荐

Metrics

本文评价