负载反-对香豆酸甲酯的醛基化普鲁兰多糖抗真菌薄膜的制备及性能

doi:10.14088/j.cnki.issn0439-8114.2025.05.019

湖北农业科学 ›› 2025, Vol. 64 ›› Issue (5): 123-127.doi: 10.14088/j.cnki.issn0439-8114.2025.05.019

负载反-对香豆酸甲酯的醛基化普鲁兰多糖抗真菌薄膜的制备及性能

崔文壮^1,2, 王伟峰^1,3, 孟宪华^1,3, 刘玉杰^1,2, 张鑫宇^1,2, 曹永红⁴, 王君^1,2, 宫矗^1,2, 杨军丽³

1.烟台中科先进材料与绿色化工产业技术研究院,山东烟台 264000;
2.烟台先进材料与绿色制造山东省实验室,山东烟台 264000;
3.中国科学院兰州化学物理研究所/中国科学院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室,兰州 730000;
4.陇南市经济林研究院花椒研究所,甘肃陇南 746000

收稿日期:2024-08-29 出版日期:2025-05-25 发布日期:2025-06-11
通讯作者: 杨军丽(1983-),男,山西阳泉人,研究员,博士,主要从事天然产物化学研究,(电子信箱)yangjl@licp.cas.cn；宫　矗（1991-），男，山东济南人，助理研究员，博士，主要从事天然源绿色功能材料研究，（电子信箱）GongChu@amgm.ac.cn。
作者简介:崔文壮（1999-）,男,山东济宁人,主要从事天然源绿色功能材料研究,（电子信箱）1632145569@qq.com
基金资助:
中央引导地方科技发展资金项目（YDZX2024038）; 山东省自然科学基金资助项目（ZR2021MB089; ZR2023QB200; ZR2023MC040）; 烟台先进材料与绿色制造山东省实验室项目（E1R03SXM04）; 烟台开发区科技领军项目（2022RC005）; 陇南市科技计划项目（2022-S·QKJ-03）

Preparation and properties of antifungal film based on aldehyde-modified pullulan loaded with methyl trans-p-coumarate

CUI Wen-zhuang^1,2, WANG Wei-feng^1,3, MENG Xian-hua^1,3, LIU Yu-jie^1,2, ZHANG Xin-yu^1,2, CAO Yong-hong⁴, WANG Jun^1,2, GONG Chu^1,2, YANG Jun-li³

1. Yantai Zhongke Research Institute of Advanced Materials and Green Chemical Engineering, Yantai 264000, Shandong, China;
2. Shandong Laboratory of Advanced Materials and Green Manufacturing at Yantai, Yantai 264000, Shandong, China;
3. Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences/Key Laboratory of Chemistry of Northwestern Plant Resources/Key Laboratory for Natural Medicine of Gansu Province, Lanzhou 730000, China;
4. Zanthoxylum Bungeanum Research Institute, Longnan Economic Forest Research Institute, Longnan 746000, Gansu, China

Received:2024-08-29 Published:2025-05-25 Online:2025-06-11

摘要/Abstract

摘要： 以反-对香豆酸甲酯和醛基化普鲁兰多糖为基质材料,采用浇铸-烘干法制备抗真菌薄膜。结果表明,抗真菌薄膜的透明性与反-对香豆酸甲酯的添加量呈负相关;使用万能材料试验机测试抗真菌薄膜的力学性能,发现反-对香豆酸甲酯的添加量越多,抗真菌薄膜的刚性越强而韧性越差。体外抗真菌活性试验表明,抗真菌薄膜对灰葡萄孢菌（Botrytis cinerea）具有较强的抗真菌活性,且其抗灰葡萄孢菌活性随着反-对香豆酸甲酯添加量的增加而逐渐增强。综上,抗真菌薄膜具有环境友好、成本低廉、制备工艺简单、力学性能适中、抗真菌活性强等优点,有望用于果蔬采后的保藏。

关键词: 抗真菌薄膜, 醛基化普鲁兰多糖, 反-对香豆酸甲酯, 灰葡萄孢菌（Botrytis cinerea）, 制备, 性能

Abstract: The antifungal film was prepared by a casting-drying method using methyl trans-p-coumarate and aldehyde-modified pullulan as the matrix material. The results showed that the transparency of the antifungal film was negatively correlated with the addition amount of methyl trans-p-coumarate. Mechanical property tests using a universal material testing machine revealed that higher amounts of methyl trans-p-coumarate increased the rigidity but reduced the toughness of the antifungal film. In vitro antifungal activity tests demonstrated that the antifungal film exhibited strong inhibitory activity against Botrytis cinerea, and its efficacy gradually enhanced with increasing methyl trans-p-coumarate content. In conclusion, the antifungal film possessed advantages such as environmental friendliness, low cost, simple preparation process, moderate mechanical properties, and strong antifungal activity, showing potential for postharvest preservation of fruits and vegetables.

Key words: antifungal film, aldehyde-modified pullulan, methyl trans-p-coumarate, Botrytis cinerea, preparation, properties

中图分类号:

S432

崔文壮, 王伟峰, 孟宪华, 刘玉杰, 张鑫宇, 曹永红, 王君, 宫矗, 杨军丽. 负载反-对香豆酸甲酯的醛基化普鲁兰多糖抗真菌薄膜的制备及性能[J]. 湖北农业科学, 2025, 64(5): 123-127.

CUI Wen-zhuang, WANG Wei-feng, MENG Xian-hua, LIU Yu-jie, ZHANG Xin-yu, CAO Yong-hong, WANG Jun, GONG Chu, YANG Jun-li. Preparation and properties of antifungal film based on aldehyde-modified pullulan loaded with methyl trans-p-coumarate[J]. HUBEI AGRICULTURAL SCIENCES, 2025, 64(5): 123-127.

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负载反-对香豆酸甲酯的醛基化普鲁兰多糖抗真菌薄膜的制备及性能

Preparation and properties of antifungal film based on aldehyde-modified pullulan loaded with methyl trans-p-coumarate

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