湖北农业科学 ›› 2021, Vol. 60 ›› Issue (11): 45-49.doi: 10.14088/j.cnki.issn0439-8114.2021.11.010

• 资源·环境 • 上一篇    下一篇

机械化学法修复后的有机污染土壤复垦试验与生态健康风险研究

曾曼1, 陈冬1,2, 胡敏3, 毛林强1, 胡林潮1, 张文艺1   

  1. 1.常州大学环境与安全工程学院,江苏 常州 213164;
    2.江苏龙环环境科技有限公司,江苏 常州 213022;
    3.中石化广州工程有限公司,广州 510600
  • 收稿日期:2019-07-02 出版日期:2021-06-10 发布日期:2021-07-15
  • 通讯作者: 张文艺(1968-),男,安徽安庆人,教授,博士,主要从事水污染控制与生态修复研究,(电话)13915046002(电子信箱)zwy@cczu.edu.cn。
  • 作者简介:曾 曼(1996-),女,江苏徐州人,在读硕士研究生,研究方向为土壤污染过程与防治研究,(电子信箱)183824576@qq.com。
  • 基金资助:
    中国石油化工股份有限公司科技计划项目(319005-7); 江苏省地矿局科技计划项目(2015-KY-2)

Study on the reclamation experiment and ecological health risk of organic polluted soil after mechanochemical remediation

ZENG Man1, CHEN Dong1,2, HU Min3, MAO Lin-qiang1, HU Lin-chao1, ZHANG Wen-yi1   

  1. 1. School of Environmental & Safety Engineering,Changzhou University,Changzhou 213164,Jiangsu,China;
    2. Jiangsu Longhuan Environmental Protection Technology Co.,Ltd.,Changzhou 213022,Jiangsu, China;
    3. Sinopec Guangzhou Engineering Co.,Ltd.,Guangzhou 510600,China
  • Received:2019-07-02 Online:2021-06-10 Published:2021-07-15

摘要: 为评估球磨机械化学法修复后的有机污染土壤复垦农作物生长及生态健康风险,通过种植水稻(Oryza sativa L.)、大豆[Glycine max (Linn.) Merr.],比较修复土壤、污染土壤、无污染土壤对农作物生长的影响,对修复土壤生态健康风险评价等方面进行研究。结果表明,污染土壤水稻生长周期比修复土壤水稻生长周期长,修复土壤水稻生长周期和无污染土壤水稻生长周期基本一致;比较农作物果实生长状况发现,无污染土壤水稻果实生长状况优于修复土壤,二者又优于污染土壤;无污染土壤大豆果实颗粒大小相同,污染土壤大豆果实颗粒大小不一;无污染土壤、修复土壤和污染土壤种植的水稻果实毒性分别为无毒、中毒、高毒。在修复后的土壤中检出挥发性、半挥发性污染物41种,污染物主要为2,4-二氯苯酚、多环芳烃等,修复土壤中2,4-二氯苯酚、苯酚的非致癌风险均低于可接受的风险水平,苯并(b)荧蒽的致癌风险也低于可接受的风险水平。由此可以看出,球磨机械化学法修复后土壤的毒性减弱,致癌、非致癌风险降低。

关键词: 污染土壤, 机械化学法, 毒理研究, 生态风险评价

Abstract: In order to evaluate the risk of crop growth and ecological health after the remediation of organic contaminated soil by ball milling mechanochemical method, the effects of remediated soil, polluted soil and pollution-free soil on the growth of crops were compared by planting rice, soybean. The results showed that the growth period of rice in polluted soil was longer than that of rice in remediated soil, and the growth period of rice in remediated soil was similar to that in non-polluted soil. Comparing the growth status of crop fruits, it was found that the growth status of fruit in non-polluted soil was better than remediated soil, both were better than polluted soil fruits; The size of soybean fruits in non-polluted soil was the same, and there were great difference among the polluted soil soybean fruits. The toxicity of rice fruits grown in non-polluted soil, remediated soil and polluted soil were non-toxic, toxic and high toxic respectively. 41 kinds of volatile and semi-volatile pollutants were detected in remediated soil, mainly 2,4-dichlorophenol and polycyclic aromatic hydrocarbons. The non-carcinogenic risk of 2,4-dichlorophenol and phenol in remediated soil was lower than acceptable. The carcinogenic risk of benzo (b) fluoranthene was also lower than the acceptable risk level. It can be seen from this, the toxicity of soil remediated by ball milling mechanochemical method is reduced, and the carcinogenic and non-carcinogenic risk is reduced.

Key words: polluted soil, mechanochemical method, toxicological studies, ecological risk assessment

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