HUBEI AGRICULTURAL SCIENCES ›› 2020, Vol. 59 ›› Issue (17): 158-160.doi: 10.14088/j.cnki.issn0439-8114.2020.17.036

• Detection Analysis • Previous Articles     Next Articles

Determination of chromium in food by ionic liquid-graphite furnace atomic absorption spectrometry

LING Yue-tao1,2, PAN Rui-hua1, WANG Yao-xue1, WANG Fan1, GUO Shao-fei1, ZHANG Lin1, ZHAO Li-yang1, XING Jun2   

  1. 1. Technology Center of Wuhan Customs District P.R.China, Wuhan 430050,China;
    2. Key Laboratory of Analytical Chemistry for Biology and Medicine, Ministry of Education/College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072,China
  • Received:2019-10-29 Published:2020-10-23

Abstract: A method for the determination of chromium in food by ionic liquid -graphite furnace atomic absorption spectrometry was established. The sample was directly dissolved in 1-butyl-3-methylimidazolium chloride ([Bmim]-Cl) and added with 0.5 mL nitric acid. The pretreatment process could be completed within 5 minutes. The solution was directly detected by graphite furnace atomic absorption spectrometry. Chromium has a good linear relationship in the range of 2.58~20.64 μg/L, under the optimized spectral conditions, the detection limit of chromium is 0.04 mg/kg, the recovery of standard addition is 92.00%~101.65%, RSD is 4.11%~6.69%. The pretreatment method is green and safe, easy to operate and fast to process, and has a wide application prospect.

Key words: hydrophilic ionic liquid, 1-butyl-3-methylimidazolium chloride, graphite furnace atomic absorption spectrometry, chromium

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