Advances in Remediation of Heavy Metal Contaminated Soils by in Situ Chemical Fixation

doi:10.14088/j.cnki.issn0439-8114.2019.01.002

Abstract

Abstract: In situ chemical immobilization remediation means that adding different allogenic materials to fix heavy metal element in soil, which is an important method to reduce the mobility and bioavailability of heavy metals. Now the passivating fixators used for in situ chemical immobilization present various types and distribute widely. There are inorganic passivators, organic passivators as well as organic- inorganic complexed passivators. The characteristics, immobilization mechanisms and remediation effects of different types of passivating fixators are summarized, the problems existing in the application process of various passivators and its development trend are analyzed at the same time, aiming to provide the reference for exploring some new multifunctional passivators.

Key words: heavy metal, in situ chemical immobilization remediation, passivators

CLC Number:

XU Hui-ting, ZHANG Wei-wen, SHEN Xu-yang, FU Ju-yang, CHEN Fei-fei, WANG Yan, YANG Meng, ZHAO Tong-he, ZHU Wei-qin. Advances in Remediation of Heavy Metal Contaminated Soils by in Situ Chemical Fixation[J]. HUBEI AGRICULTURAL SCIENCES, 2019, 58(1): 10-14.

References 55

[1]	周怀东,彭文启.水环境与水环境修复[M].北京:化学工业出版社,2005.
[2]	刘永杰,胡振华,刘永兵,等.海南岛河流底泥肥力和重金属污染特征及其风险评价[J].中国水土保持科学,2017,15(3):131-138.
[3]	胡兰文,陈明,杨泉.底泥重金属污染现状及修复技术进展[J].环境工程,2017,35(12):115-118,12.
[4]	唐浩,曹乃文.浅谈我国土壤重金属污染现状及修复技术[J].安徽农学通报,2017,23(7):103-105.
[5]	李玉宝,夏锦梦,论东东.土壤重金属污染的4种植物修复技术[J].科技导报,2017,35(11):47-51.
[6]	张敏,郜春花,李建华,等.重金属污染土壤生物修复技术研究现状及发展方向[J].山西农业科学,2017,45(4):674-676.
[7]	夏星辉,陈静生.土壤重金属污染治理方法研究进展[J].环境科学,1997,18(3):72-76.
[8]	何光俊,李俊飞,谷丽萍.河流底泥的重金属污染现状及治理进展[J].水利渔业,2007,153(5):60-62.
[9]	郭观林,周启星,李秀颖.重金属污染土壤原位化学固定修复研究进展[J].应用生态学报,2005,16(10):1990~1996.
[10]	曹心德,魏晓欣,代革联,等.土壤重金属复合污染及其化学钝化修复技术研究进展[J].环境工程学报,2011,5(7):1441-1458.
[11]	GUO G,ZHOU Q,LI X.Advances in research on in situ chemo-immobilization of heavy metals in contaminated soils[J].PubMed,2005,16(10):1990-1996.
[12]	李欣芮,成杰民.原位钝化修复技术在重金属污染土壤中的可行性探究[J].绿色科技,2017,(20):87-89.
[13]	LOMBI E,HAMON R E,MCGRATH S P,et al.Lability of Cd,Cu,andZnin polluted soils treated with lime,bcringitc,and red mud andidcntificalion of a non-labile colloidal fraction of metals usingisotopic techniques[J].Environmentnl Science and TechnoLogy,2003,37(5):979-984.
[14]	MADRID F,ROMERO A S,MADRID L,et al.Reduction of availability oftrace metals inurban soils using inorganic amendments[J].Environmental Geochemistry and Health,2006,28:365-373.
[15]	CASTALDI P,SANTONA L,MELIS P.Heavy metal immobilization bychemical amendments in a polluted soil and influence on whitelupingrowth[J].Chemosphere,2005,60(3):365-371.
[16]	KOSTAS K,DIMITRA Z,IOANNIS P,et al.Assessment of pistachio shell biochar quality and its potential for adsorption of heavy metals[J].Waste Biomass Valor,2015,6:805-816.
[17]	张峰,马烈,张芝兰,等.化学还原法在Cr污染土壤修复中的应用[J].化工环保,2012,32(5):419-423.
[18]	HALE B,EVANS L,LAMBERT R. Effects of cement or lime on Cd,Co,Cu,Ni,Pb,Sb and Zn mobility in field-contaminated and aged soils[J].Journal of Hazardous Materials,2012,199-200:119-127.
[19]	王萍. 不同钝化剂对重金属污染土壤长期稳定化效果研究[D].陕西杨凌:西北农林科技大学,2017.
[20]	吴烈善,曾东梅,莫小荣,等.不同钝化剂对重金属污染土壤稳定化效应的研究[J].环境科学,2015,36(1):309-313.
[21]	MALLAMPATI S R,MITOMA Y,OKUDA T,et al.Enhanced heavy metalimmobilization in soil by grinding with addition of nanometallic Ca/CaO dispersion mixture[J].Chemosphere,201289:717-723.
[22]	DU Y J,WEI M L,REDDY K R,et al.New phosphate-based binderfor stabilization of soils contaminated with heavy metals:Leaching,strength and microstructure characterization[J].Journal ofEnvironmental Management,2014,146:179-188.
[23]	雷鸣. 两种含磷物质对土壤重金属和砷向水稻迁移的影响[D].长沙:中南林业科技大学,2014.
[24]	CUI H B,ZHOU J,SI Y B,et al.Immobilization of Cu and Cd in acontaminated soil:one-and four-year field effects[J].Journal of Soils and Sediments,2014,14:1397-1406.
[25]	李剑睿,徐应明,林大松,等.农田重金属污染原位钝化修复研究进展[J].生态环境学报,2014,23(4):721-728.
[26]	李雪婷,黄显怀,周超,等.改性黏土矿物修复重金属污染底泥的稳定化试验研究[J].环境工程,2015,9(33):158-163.
[27]	BRAMRYD T.Long-term effects of sewage sludge application on theheavy metal concentrations in acid pine (Pinussylvestris L.) forestsin a climatic gradient in Sweden[J].Forest Ecology andManagement,2013,289(1):434-444.
[28]	高瑞丽,唐茂付,庆灵,等.生物炭、蒙脱石及其混合添加对复合污染土壤中重金属形态的影响[J].环境科学,2017(1):361-367.
[29]	殷飞. 重金属复合污染土壤固定修复中钝化剂筛选及其作用机制[D].昆明:昆明理工大学,2015.
[30]	LEE S H,JL W H,LEE W S,et al.Influence of amendments and aided phytostabilization on metal availability and mobility in Pb/Zn mine tailings[J].Journal of Environmental Management,2014,139:15-21.
[31]	尹鹏. 改性工业废渣对重金属污染土壤的稳定化修复研究[D].广州:华南理工大学,2015.
[32]	LOPAREVA-POHU A,POURRUT B,WATERLOT C,et al.Assessnment of flyash-aided phytostabilisation of highly contaminated soils afer an 8-year field trial:part 1.Influence on soil paramters and metalextractability[J].Science of the total environment,2011,409(3):647-654.
[33]	PARK J H,LAMB D,PANEERSELVAM P,et al.Role of organicamendments on enhanced bioremediation of heavy metal (loid)contaminated soils[J].Journal of Hazardous Materials,2011,185:549-574.
[34]	周利强,吴龙华,骆永明,等.有机物料对污染土壤上水稻生长和重金属吸收的影响[J].应用生态学报,2012(2):383-388.
[35]	KOUPING L,XINGY,GERTY G,et al.Effect of bamboo and rice straw biochars on the mobility and redistribution of heavy metals(Cd,Cu,Pb and Zn) in contaminated soil[J].Journal of Environmental Management,2017,186(2):285-292.
[36]	周波,唐劲驰,张池,等.不同物料蚓粪对土壤酸度和Cu、Pb化学形态的影响[J].水土保持学报,2017(4):311-319.
[37]	GANG Y,ZHANG H W,QI M X,et al.Effects of pyrolysis temperature on the physicochemical properties of biochar derived from vermicompost and its potential use as an environmental amendment[J].RSC Advances,2015,5(50):40117-40125.
[38]	顾巧浓,金红丽,周玲玲.钝化剂对土壤重金属污染修复的实验研究[J].能源与节能,2015,(11):105-106,155.
[39]	茹淑华,耿暖,徐万强,等.有机-无机复合钝化剂对污染土壤中Cd和Pb有效性的影响[J].河北农业科学,2017,21(1):85-90.
[40]	陈远其,张煜,陈国梁.石灰对土壤重金属污染修复研究进展[J].生态环境学报,2016,25(8):1419-1424.
[41]	BASTA N T,GRADWOHL R,SNETHEN K L,et al.Chemical immo-bilization of lead,zinc and cadmium in smelter contaminated soilsusingbiosolids and rock phosphate[J].Environ Qual,2001,30:1222-1230.
[42]	郭晶晶. 蒙脱石/零价铁纳米复合材料修复水体重金属污染效率及机理研究[D].呼和浩特:内蒙古大学,2014.
[43]	杨俊兴,陈世宝,郭庆军.赤泥在重金属污染治理中的应用研究进展[J].生态学杂志,2013,32(7):1937-1944.
[44]	王耀,梅向阳,段正洋,等.生物炭及其复合材料吸附重金属离子的研究进展[J].材料导报,2017,31(10):135-143.
[45]	王邦芬,张崇玉.不同钝化剂对鸡粪有机肥还田重金属(Cd、Cr、Pb)的钝化作用[J].广东农业科学,2015(8):44-50.
[46]	CHIRENJE T,MA L Q.Effects of Acidification on Metal Mobility in a Papermill-Ash Amended Soil[J].Journal of Environmental Quality,1999,28:760-767.
[47]	HSU J H,LO S L.Characterization and Extractability of Copper,Manganese,and Zinc in Swine Manure Composts[J].Journal of Environmental Quality,2002,9(2):447-453.
[48]	徐龙君,袁智.外源镉污染及水溶性有机质对土壤中Cd形态的影响研究[J].土壤通报,2009,40(6):1442-1445.
[49]	CORAMI A,MIGNARDI S,FERRINI V.Cadmium removal from single-and multi-metal(Cd+Pb+Zn+Cu) solutions by sorption on hydroxyapatite[J].Journal of Colloid and Interface Science,2008,317(2):402-408.
[50]	CHEN X B,WRIGHT J V,CONCA J L,et al.Effects of pH on heavy metal sorption on mineral apatite[J].Environmental Science and Technology,1997,31(3):624-631.
[51]	纪冬丽,张竞,孟凡生,等.共存离子对EK/PRB联合修复砷污染土壤的影响[J].环境工程学报,2018,12(1):172-177.
[52]	王碧玲,谢正苗,孙叶芳, 等.磷肥对铅锌矿污染土壤中铅毒的修复作用[J].环境科学学报,2005(9):1189-1194.
[53]	GARRIDO F,ILLERA V,GARCÍA-GONZÁLEZ M T.Effect of the addition of gypsum-and lime-rich industrial by-products on Cd,Cu and Pb availability and leachability in metal-spiked acid soils[J].Applied Geochemistry,2005,20(2):397-408.
[54]	黄增,黄红铭,许园园,等.Pb、As复合污染土壤中钝化剂的筛选及其工艺条件优化研究[J].应用化工,2017,46(10):1967-1969.
[55]	吴宝麟,杨志辉,柴立元,等.磷基及铁基钝化剂对Pb、Cd、As复合污染土壤的修复效果及其工艺条件优化[J].安全与环境学报,2015,15(5):314-319.