Analysis of phthalate esters pollution in soils of facility vegetable bases of Yangling

doi:10.14088/j.cnki.issn0439-8114.2021.13.024

Abstract

Abstract: In order to evaluate the pollution status of phthalate esters （PAEs） in soils of Yangling facility vegetable bases, 15 PAEs were detected and analyzed in soil samples by gas chromatography-mass spectrometry. The results showed that 12 PAEs were detected in the analyzed soil samples, the total contents of which ranged from 53.4 μg/kg to 3 524.1 μg/kg, with an average value of 602.7 μg/kg. The detection rates of DEHP, DBP, DIBP, DMEP, BBP, DNOP were 100%, 100%, 100%, 73.3%, 63.3%, 53.3%, respectively. And their average contents were 286.3, 167.3, 123.1, 157.6, 121.3, 130.5 μg/kg, respectively. Compared with soils in other regions,the pollution level of PAEs in vegetable base soils of Yangling is lower, but such compounds are ubiquitous in facility vegetable base soils, and the potential environmental risks should be paid attention to.

Key words: phthalate esters （PAEs）, vegetable base, soil, pollution condition

CLC Number:

X825

LI Guo-xiu, CUI Li-hui, LIU Wei, LIU Xiao-ning. Analysis of phthalate esters pollution in soils of facility vegetable bases of Yangling[J]. HUBEI AGRICULTURAL SCIENCES, 2021, 60(13): 119-122.

References

[1] 邱东茹,吴振斌,贺锋.内分泌扰乱化学品对动物的影响和作用机制[J].环境科学研究,2000,13(6):52-55.
[2] MOORE R W, RUDY T A, LIN T M, et al.Abnormalities of sexual development in male rats with in utero and lactational exposure to the antiandrogenic plasticizer Di(2-ethylhexyl) phthalate[J]. Environmental health perspectives,2001,109(3): 229-237.
[3] 林兴桃,王小逸,任仁.环境内分泌干扰物——邻苯二甲酸酯的研究[J].环境污染与防治,2003,25(5):286-288.
[4] PEIJNENBURG W J G M, STRUIJS J. Occurrence of phthalate esters in the environment of the Netherlands[J]. Ecotoxicology and environmental safety, 2006, 63(2): 204-215.
[5] GIBSON R, WANG M J, PADGETT E, et al.Analysis of 4-nonylphenols, phthalates, and polychlorinated biphenyls in soils and biosolids[J]. Chemosphere, 2005, 61(9): 1336-1344.
[6] 陈佳祎,李成,栾云霞,等.北京设施蔬菜基地土壤中邻苯二甲酸酯的污染水平及污染特征研究[J].食品安全质量检测学报,2016,2(7):472-477.
[7] 玛合巴丽·托乎塔尔汉,张雁鸣,沈琦,等.瓜田土壤中邻苯二甲酸酯的污染特征及其健康风险评估[J]. 现代食品科技,2020,26(11):287-294.
[8] 郇志博,王晓燕,田海,等.海南省11个市县设施农业土壤邻苯二甲酸酯类塑化剂污染状况及健康风险[J].热带作物学报,2021,42(3): 806-815.
[9] 周斌. 黄淮海地区农田土壤邻苯二甲酸酯污染特征与成因研究[D].北京:中国农业科学院,2020.
[10] VIKELSOE J, THOMSEN M, CARLSEN L.Phthalates and nonylphenols in profiles of differently dressed soils[J]. Science of the total environment, 2002, 296(1-3): 105-116.
[11] 李彬,吴山,梁金明,等.中山市农业区域土壤-农产品中邻苯二甲酸酯(PAEs)污染特征[J].环境科学,2015,36(6):2284-2291.
[12] 李海峰,任红松,刘河江,等.农业土壤邻苯二甲酸酯污染对农产品质量安全的影响及其防治对策[J].江西农业学报,2020,32(7):85-89.
[13] GB5009.271-2016,食品安全国家标准食品中邻苯二甲酸酯的测定[S].
[14] 王晓燕,郇志博.气相色谱-串联质谱法测定土壤中16种邻苯二甲酸酯和2种邻苯二甲酸酯单酯代谢物[J]. 理化检验-化学分册,2020(56):799-803.
[15] NIU L L,XU Y,XU C,et al. Status of phthalate esters contamination in agricultural soils across China and associated health risks[J/OE]. Environ pollut,2014,8:195:16-23.DOI:10.1016/j.envpol. 2014. 08.014.
[16] CHAI C,CHENG H Z,GE W,et al.Phthalic acid esters in soils from vegetable greenhouses in Shandong peninsula, East China[J]. Plos one,2014,9(4). DOI:10.1371/ journal.pone.0095701.
[17] 杨国义,张天彬,高淑涛,等.广东省典型区域农业土壤中邻苯二甲酸酯含量的分布特征[J].应用生态学报, 2007,18(10):2308-2312.
[18] 赵胜利,杨国义,张天彬,等.珠三角城市群典型城市土壤邻苯二甲酸酯污染特征[J].生态环境学报,2009,18(1):128-133.
[19] 郑晓英,周玉文.北京城市污泥中邻苯二甲酸酯的研究[J].北京工业大学学报, 2006,4(32): 343-346.
[20] New York State Department of Environmental Conservation.SVOCs soil cleanup objectives[R/OL]. Appendix A of TAGM#4046. http://www.dec.ny.gov/regulations /30566.html.2010-03-24.